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The energy content in fuels is often measured in BTU (British Thermal Units).

I'm assuming that you're talking about compressed natural gas, as in the form that is used in some cars like the Honda Civic GX.

One gallon of compressed natural gas contains 138,700 BTU.

One gallon of gasoline contains 125,000 BTU.

[http://www.bts.gov/publications/national_transportation_statistics/2002/html/table_04_06.html]

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