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Enterprise: The prototype that never went to space.

Columbia: First shuttle launched to orbit, STS-1. Destroyed STS-107 after a piece of foam broke off the external fuel tank, and smashed a hole in the wing. The sad thing is all they would have had to do to catch the damage is an EVA outside of the cargo bay.

Challenger: Second shuttle launched to orbit, STS-6. Exploded STS-51-L just after launch. Several ranking engineers advise that the launch be canceled, but military and public relations refused to scrub the launch. The engineers who tried to warn NASA about the danger were promptly fired for whistle-blowing. When the crew compartment was recovered in the Atlantic Ocean, just off the Florida coast, they found that at least 3 of the 7 crew actually survived the explosion, and the subsequent crash, and had drowned. They suffered extreme burns, numerous broken bones, injuries caused by explosive decompression of the cabin (altitude was over 10 miles at the blast), and massive shock trauma from the impact with the water at over 300 mph. There's no way they were conscious, and there wouldn't have been any way to help them.

Discovery: First launch STS-41-D. Launched the Hubble Space Telescope, STS-31.

And Endeavor: First launched STS-49.

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