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Because the energy comes from free carbon and oxygen that produce heat when they are recombined to form CO2 (carbon dioxide).

The fossil fuel contains hydrocarbons that can be burned to produce CO2, water and heat. The fossil fuel material was formed millions of years ago by photosynthesis, when plants took in CO2 and separated the carbon from the oxygen, using the Sun's rays. The carbon was used in the production of tissues for the planets, and the oxygen was released into the atmosphere.

So the energy that comes from burning fossil fuels came originally from the Sun by photosynthesis.

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