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DNA basically contains double helical chains comprising of a specific sequence of amino acids. The chains are attached by hydrogen bonds between complimentery bases: A-T, G-C That way, proteins appear to be simpler since they (usually) contain linear polypeptide chains with fewer cross links. But globular proteins can have a lot of cross linking through intermolecular forces between the polypeptide chains and therefore also have double helical structure like DNA. thus no comparision in this case. But fibrous proteins are much simpler. So unless you actually specify the particular protein under reference, the comparision would be indeed vague.

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Q: Is DNA a structurally simpler molecule than protein?
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