Often electrochemical studies are interested in one of the electrodes of the cell only.
The second electrode is present to complete the cell.
Electrode of interest is named working electrode or the indicator electrode; the
second electrode is know as reference electrode or auxiliary electrode (counter
electrode).
Potentiometric titration is a method to detect potential difference between the indicator electrode and reference electrode and thus determine concentration of chemical component, which reacts with reagent added to a solution potentially in equilibrium at the beginning.The popularly used reference electrode is either silver-silver chloride or mercury sulfate electrode, and the indicator electrode is generally made of glass electrode, platinum electrode and silver electrode or ion selective electrode.
Platinum electrode is used as the indicator electrode in potentiometry titration to measure the potential difference between the indicator electrode and the reference electrode. It provides a stable and reproducible potential during the titration process, allowing for accurate determination of the equivalence point. Platinum electrodes are inert and do not participate in the redox reactions happening during the titration, making them suitable for a wide range of titrations.
A pH electrode works by measuring the electrical potential difference between a reference electrode and a glass electrode. The glass electrode is sensitive to hydrogen ions in the solution, which determines the acidity or alkalinity. The pH value is calculated based on this potential difference.
A pH electrode works by measuring the electrical potential difference between a reference electrode and a glass electrode. The glass electrode contains a special membrane that responds to changes in hydrogen ion concentration, which is used to determine the pH of a solution.
A pH meter typically consists of a probe with a glass electrode, a reference electrode, and a meter that displays the pH value. The glass electrode measures the hydrogen ion concentration in a solution, while the reference electrode provides a stable reference point. The meter then calculates and displays the pH value based on the difference in electrical potential between the two electrodes.
Potentiometric titration is a method to detect potential difference between the indicator electrode and reference electrode and thus determine concentration of chemical component, which reacts with reagent added to a solution potentially in equilibrium at the beginning.The popularly used reference electrode is either silver-silver chloride or mercury sulfate electrode, and the indicator electrode is generally made of glass electrode, platinum electrode and silver electrode or ion selective electrode.
Platinum electrode is used as the indicator electrode in potentiometry titration to measure the potential difference between the indicator electrode and the reference electrode. It provides a stable and reproducible potential during the titration process, allowing for accurate determination of the equivalence point. Platinum electrodes are inert and do not participate in the redox reactions happening during the titration, making them suitable for a wide range of titrations.
A pH electrode works by measuring the electrical potential difference between a reference electrode and a glass electrode. The glass electrode is sensitive to hydrogen ions in the solution, which determines the acidity or alkalinity. The pH value is calculated based on this potential difference.
A pH electrode works by measuring the electrical potential difference between a reference electrode and a glass electrode. The glass electrode contains a special membrane that responds to changes in hydrogen ion concentration, which is used to determine the pH of a solution.
An auxiliary electrode is used in electrochemical cells to facilitate measurements or control reactions without interfering with the primary electrode's function, often serving as a reference or measuring point. In contrast, a ground electrode is connected to the earth or a common reference point, providing a stable voltage reference for electrical circuits and ensuring safety by dissipating excess charge. Essentially, the auxiliary electrode aids in specific measurements, while the ground electrode serves as a safety and reference point in electrical systems.
A pH meter typically consists of a probe with a glass electrode, a reference electrode, and a meter that displays the pH value. The glass electrode measures the hydrogen ion concentration in a solution, while the reference electrode provides a stable reference point. The meter then calculates and displays the pH value based on the difference in electrical potential between the two electrodes.
E(SCE)-E(H)=241 mV @25°C SHE is a primary standard electrode bt SCE is secondary reference electrode use for more easier work than SHE & SCE,s potential also measured by taking SHE as reference electrode.
what is the difference between the external & internal indicator
Mercury is placed at the bottom of a calomel electrode to provide a stable and well-defined interface between the electrode and the electrolyte solution. This helps to maintain a consistent potential at the electrode/solution interface, making it a reliable reference electrode in electrochemical measurements.
Distinguish between buffer and indicator
Direct potentiometry is a method of measuring the concentration of ions in a solution by directly measuring the potential difference between an ion-selective electrode and a reference electrode. It is a simple and rapid technique that is commonly used in the analysis of various ions in solutions.
pH electrodes work by measuring the electrical potential difference between a reference electrode and a glass electrode in contact with the solution. The glass electrode responds to the hydrogen ion concentration in the solution, which is directly related to its acidity or alkalinity. The pH value is then calculated based on this potential difference, providing a measure of the solution's acidity or alkalinity.