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At a molecular level, water becomes more dense as it approaches freezing. Though physically it does not appear so. If it did it would slowly become gellular, which we all know doesn't happen. Basically, the molecules become slower and form a tighter formation (becomming more like a solid, but still very much a liquid), arguably beccoming a better conductor for heat and electricity.

When water approaches its freezing point, the H-O-H (H20) molecules start to slow down. In liquid form, they move close together, but they are more free from each other and can still move about and fill different shapes. Once the water freezes, the molecules appear to stop moving completely (but they are moving, just in extremely small ammounts). They lock together, so to say, and have now formed a solid.

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