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Sulfuric acid has hydrophilic properties when concentrated, so it may have some effect on the reaction taking place. Oxalic acid is an reducing agent, so in titrations - which usually involve some kind of redox - it may begin reacting in ways not intended.

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Why there is a need to warm the solution of sulfuric acid and oxalic acid during redox titration?

Warming the solution of sulfuric acid and oxalic acid during redox titration increases the reaction rate, making the titration process faster and more efficient. The elevated temperature helps to ensure that the reaction between the two compounds proceeds to completion, resulting in more accurate and reliable titration results.


Why you use dilute H2SO4 in titration permanganat and oxalic acid?

Dilute sulfuric acid is used in the titration of potassium permanganate with oxalic acid because it helps to maintain a stable pH and prevents the oxidation of oxalic acid by permanganate ions. This ensures accurate results by minimizing side reactions and interference.


Why oxalic acid is heated before titration with KMnO4?

Heating oxalic acid before titration with KMnO4 helps to remove any water of crystallization, making the compound anhydrous. This ensures accurate measurement of the substance being titrated and helps to prevent interference from water during the titration process. Additionally, heating can help to dissolve the oxalic acid more effectively, ensuring a more efficient reaction during titration.


Why do you add sulfuric acid to an oxalic solution?

Oxalic acid is an organic covalent compound not very much soluble in water during its titration with an oxidizing agent as KMnO4 its decomposition is required into CO and CO2 along with removal of water, sulphuric acid makes this process possible.


Why potassium permanganate is used as a self indicator in the titration of oxalic acid?

Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.

Related Questions

Why there is a need to warm the solution of sulfuric acid and oxalic acid during redox titration?

Warming the solution of sulfuric acid and oxalic acid during redox titration increases the reaction rate, making the titration process faster and more efficient. The elevated temperature helps to ensure that the reaction between the two compounds proceeds to completion, resulting in more accurate and reliable titration results.


Why 2N sulphuric acid is used in oxalic acid estimation?

This titration is based on the neutralization reaction between oxalic acid and sulfuric acid; a pH indicator is used.


Why you use dilute H2SO4 in titration permanganat and oxalic acid?

Dilute sulfuric acid is used in the titration of potassium permanganate with oxalic acid because it helps to maintain a stable pH and prevents the oxidation of oxalic acid by permanganate ions. This ensures accurate results by minimizing side reactions and interference.


Why oxalic acid is heated before titration with KMnO4?

Heating oxalic acid before titration with KMnO4 helps to remove any water of crystallization, making the compound anhydrous. This ensures accurate measurement of the substance being titrated and helps to prevent interference from water during the titration process. Additionally, heating can help to dissolve the oxalic acid more effectively, ensuring a more efficient reaction during titration.


Why do you add sulfuric acid to an oxalic solution?

Oxalic acid is an organic covalent compound not very much soluble in water during its titration with an oxidizing agent as KMnO4 its decomposition is required into CO and CO2 along with removal of water, sulphuric acid makes this process possible.


Why potassium permanganate is used as a self indicator in the titration of oxalic acid?

Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.


How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?

In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.


Why oxalic acid is acidified before titration?

Oxalic acid is acidified before titration to provide a medium that favors the reaction of the analyte with the titrant while minimizing interference from other substances. Acidification ensures that the oxalic acid dissociates fully to its acidic form, allowing for a more accurate and precise titration.


Why you heat oxalic acid and sulphuric acid solution?

Heating oxalic acid and sulfuric acid solution can help in the formation of carbon monoxide and carbon dioxide gases. This process is often used in the laboratory to generate these gases for various chemical reactions or analytical purposes.


What indicator can you choose for the titration of oxalic acid with sodium hydroxide?

Phenolphthalein is a suitable indicator for the titration of oxalic acid with sodium hydroxide. It changes color from colorless to pink at the endpoint of the titration when the acid has been completely neutralized.


Which indicator is used in titration of oxalic acid with HCl?

Both HCl and oxalic acid are acids. Therefore, since there is no alkali present, these compounds do not undergo neutralization. So there is no suitable indicators for the addition of these two reagents.


Why is phenolphthalein indicator used in the titration of oxalic acid against sodium hydroxide?

Phenolphthalein is used as an indicator in the titration of oxalic acid against sodium hydroxide because it undergoes a color change at the pH region where the reaction between oxalic acid and sodium hydroxide is neutralized. Oxalic acid is a diprotic acid, meaning it requires two equivalents of sodium hydroxide to be fully neutralized. Phenolphthalein changes color at a pH of around 8.2-10, which is ideal for indicating the endpoint of the titration.