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The electrostatic force exerted by a cation on an anion distorts its electron cloud, which has a tendency to move towards the cation. The degree of polarisation is directly proportional to the charge of the cation and indirectly proportional to its size.
Due to polarization, the ionic compound gains a certain degree of covalency.

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14y ago
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15y ago

Polarization has to do with how the electrons are being shared in a covalent bond. When two atoms with different electronegativities bond together, the valence electrons are unevenly shared between them. The more electronegative atom will pull the electrons of the bond closer to itslef because it has a strong "desire" for those electrons, thus making the bond polar.

Ex: HCF3 or trifluoromethane. The electrons between the carbon and fluorine reside closer to the fluorine because fluorine is more electronegative.

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Q: How does polarisation occur in ionic compounds?
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