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2Mg^2+ + O2 -- > 2MgO

This is the chemical reaction occurring when burning magnesium. When burning the metal in air, which is slightly less than 20% O2, there is less O2 for the Mg to react with than there would be in a pure O2 environment.

In the high O2 concentration environment the Mg doesn't have to "wait" for more O2 to diffuse into the area before the reaction can occur. In the case of burning Mg in air, the O2 conc. is much lower, and therefore depleted faster, and in turn must "wait" for more O2 to diffuse into the area.

The reason it seems to burn hotter and bright is because all the energy being release from the combustion is able to happen much faster in the pure O2 environment.

Provided you were burning the same mass of Mg, the same TOTAL amount of energy is released in both reactions, the pure O2 environment just allows it to happen in a shorter time frame.

Energy released reacting (enthlapy of combustion)1 mol of Mg = -1200 kJ/mol regardless of the O2 saturation in the environment. Reacting it in a pure oxygen environment just allows the reaction to happen faster.

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