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Different temperatures are necessary to melt different solder alloys:

Tin/Lead alloy 63 Sn 37Pb requires 361 oF or 183 oC

Tin/Silver alloy 97Sn 3 Ag requires 430 oF or 221 oC

Tin/Lead/Silver alloy 62Sn 36Pb 2Ag requires 354 F 179 oC

If the iron's tip is much hotter the metals easily oxidize faster.

Note: remember that the temperature control on a soldering station is not the same as an on/off switch: if you want to the temperature of the tip to change, you have to allow sufficient time for heating-up or cooling-down after you have changed the setting of the temperature control. Look at the little indicator light to be sure it's on and is not blinking to show the set temperature has not yet been reached.

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