By reaction with alcoholic KOH (the reaction will be an example of dehydrohalogenation)
method 1: propyne + H2 on Pt catalyst => propane. then do free radical halogenation with Br2, which will prefer to add to the most substituted carbon atom, giving 2-bromopropane
method 2: propyne + H2 on poisoned catalyst (ex Lindlar's) => propene. next do oxymecuration/demercuration (which tends to give you the more substituted alcohol) to yield isopropanol. next, brominate with HBr or P + Br2 or PBr3, etc to yield 2-bromopropane.
1-bromopropane is CH2BrCH2CH3. The Br is removed as HBr molecule by adding alcoholic KOH as the reagent. This would result in 1-propene CH2=CHCH3. Then hydrobromination is done by adding HBr. H would add to the terminal C according to Markovnikov's rule. This would give 2-bromopropane CH3CHBrCH3.
React 2-chloro propane with NaOHaq. the produced 2-propanol when reacts with HBr you may get the 2-bromo propane.
1. CH3-CH(Cl)-CH3 + NaOH -----> CH3-CH(OH)-CH3 + NaCl
2. CH3-CH(OH)-CH3 + HBr ------> CH3-CH(Br)-CH3 + H2O
The Dehydrohaogenation of 1-bromo propane with alcoholic KOH gives propene which on again hydrohalogenation with HBr gives 2-bromo propane due to Markonikove's rule for addition.
1st convert 1 bromoropane to its corresponding grignard reagent the treat with water athen we get bromane we treat it with HBr to and by markonikoff rule we get 2-bromo propane
Electrophilic addition reaction
Answer
(propene) (2-chloropropane)
HCl
React with alcoholic KOH (dehydrohalogenation) to give 1-propene, followed by treatment with HCl (electrophilic addition).
benzene with 2~chloropropane in presence of aluminiumchloride
first treat the PROPENE with HBR to form 2-bromopropane. And then treat it with Na in the presence of dry ether to get 2,3-dimethyl butane
(propene) (2-chloropropane)
HCl
React with alcoholic KOH (dehydrohalogenation) to give 1-propene, followed by treatment with HCl (electrophilic addition).
2-chloropropane to 2,3-dimethyl butane
benzene with 2~chloropropane in presence of aluminiumchloride
first treat the PROPENE with HBR to form 2-bromopropane. And then treat it with Na in the presence of dry ether to get 2,3-dimethyl butane
only two structural isomers are possible, 1-chloropropane and 2-chloropropane
C3H7Cl
4-methylpent-2-yne is the product formed by the reaction of propylide ion and 2-chloropropane.
4-methylpent-2-yne is the product formed by the reaction of propylide ion and 2-chloropropane.
Oxymercuration. Add Hg(OAc)2 to make any alkene a secondary alcohol or make the OH go on the most substituted Carbon. a.k.a. Markarvnikov addition of OH.
CH3- CHCl - CH3 is '2-chloropropane'