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Chlorine is more electromagnetic than bromie, the C-Cl bond is more polar than the C-Br. The permanent dipole is stronger between 1-chloropropane molecules, so more energy is required to break these intermolecular bonds. The boiling point of 1-chloropropane is higher than 1-bromopropane.

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Q: How would you expect the boiling points of propane and 1-chloropropane to compare?
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