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Both Li and K lose electrons to get noble gas configuration. Br gains an electron to get noble gas configuration. So K is more likely to form a compound with Br.

Potassium is a metal in group 1. It usually forms ionic compounds with other non metallic elements. From these elements, it is more likely to bond with bromine. Recall that lithium is as in the same family as potassium.

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Which pair of elements are most likely to form an ionic compound P and Br or Zn and K?

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