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Without being acted on by an external charge your skin is neutral.

In some cases a static charge may build up on your skin, in which case your skin could be either positive or negative. This is what happens when you rub a balloon on your hair and it sticks to you.

The skin-effect is another case where a very high frequency alternating current travels only through the outermost portions of the conductor. The effect applies to all conductors, but in the case of your actual skin the current flows only through the very topmost portions. Even with amounts of current that would normally be enough to kill or injure a person, the high frequency AC electricity may pass harmlessly over the top of your skin.

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