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Why phenol more acidic than aliphatic alcohol and water?
Phenol is more acidic than aliphatic alcohols and water because the benzene ring stabilizes the phenoxide ion formed upon deprotonation, making it more favorable to lose a proton. This stabilization is due to resonance delocalization of the negative charge in the phenoxide ion. In aliphatic alcohols and water, there is no such resonance stabilization, resulting in weaker acidity.
Why is phenol more soluble in aqueous NaOH than in water?
Phenol is acidic in nature. The phenolate anion is stable through resonance. Hence, an acid base reaction ensues between phenol and NaOH in water resulting in the formation of sodium phenolate, which is highly soluble in water compared to phenol.
Which is more acidic p-chloro phenol or p-fluoro phenol?
p-chloro phenol is more acidic thisi is because in p-fluoro phenol as fluorine and carbon have identical 2p orbitals, the overlapping is perfect Hence the +r effect and -I effect cancels thus making it less acidic
Is 1-hexanol more acidic or less acidic than phenol?
Phenol is more acidic than 1-hexanol because the hydroxyl group in phenol is directly attached to the aromatic ring, which stabilizes the resulting phenoxide ion through resonance. In contrast, the hydroxyl group in 1-hexanol is attached to an aliphatic chain, making it less acidic.
What are the key differences between phenol and benzene in terms of their chemical properties and reactivity?
Phenol and benzene are both aromatic compounds, but phenol has a hydroxyl group (-OH) attached to the benzene ring, making it more reactive than benzene. Phenol can undergo reactions such as oxidation and substitution more readily than benzene. Additionally, phenol is more acidic than benzene due to the presence of the hydroxyl group.
Why phenol more acidic than aliphatic alcohol and water?
Phenol is more acidic than aliphatic alcohols and water because the benzene ring stabilizes the phenoxide ion formed upon deprotonation, making it more favorable to lose a proton. This stabilization is due to resonance delocalization of the negative charge in the phenoxide ion. In aliphatic alcohols and water, there is no such resonance stabilization, resulting in weaker acidity.
Why is phenol more soluble in aqueous NaOH than in water?
Phenol is acidic in nature. The phenolate anion is stable through resonance. Hence, an acid base reaction ensues between phenol and NaOH in water resulting in the formation of sodium phenolate, which is highly soluble in water compared to phenol.
Which is more acidic phenol or para-chloro phenol?
Phenol. Anisole doesn't have any acidic protons.
Why phenol is more acidic than ethanol?
phenol is more acidic because of the benzene ring present in the molecule,when you lose the H form the OH group it is possible to delocalise the charge around the aromatic system due to the pi electron cloud,straight chain alcohols cannot do this so it is less favourable to deprotonate them hance it is easier to deprotonate a phenol,hence we say it is more acidic
Which is more acidic p-chloro phenol or p-fluoro phenol?
p-chloro phenol is more acidic thisi is because in p-fluoro phenol as fluorine and carbon have identical 2p orbitals, the overlapping is perfect Hence the +r effect and -I effect cancels thus making it less acidic
Is 1-hexanol more acidic or less acidic than phenol?
Phenol is more acidic than 1-hexanol because the hydroxyl group in phenol is directly attached to the aromatic ring, which stabilizes the resulting phenoxide ion through resonance. In contrast, the hydroxyl group in 1-hexanol is attached to an aliphatic chain, making it less acidic.
What are the key differences between phenol and benzene in terms of their chemical properties and reactivity?
Phenol and benzene are both aromatic compounds, but phenol has a hydroxyl group (-OH) attached to the benzene ring, making it more reactive than benzene. Phenol can undergo reactions such as oxidation and substitution more readily than benzene. Additionally, phenol is more acidic than benzene due to the presence of the hydroxyl group.
Suggest a chemical test(s) to distinguish ethanol and phenol. Include the reagents reaction conditions and observations. And the equation?
Phenol solution, or phenol directly from the manufacturer?If the phenol is in the form it comes in from the factory, no chemical test is necessary. Phenol is a white crystalline solid.If it's dissolved in water, the easiest test is pH. Phenol solution is more acidic than ethanol. So...whatever you use for a pH test will do ya.
Which is strong acid water or phenol?
A strong acid is typically stronger than phenol in terms of acidity due to its ability to fully dissociate in water to release protons. Phenol is a weak acid that only partially dissociates in water, making it less acidic compared to strong acids like hydrochloric acid or sulfuric acid.
Why are phenols acidic in nature?
Phenol can act as an acid due to it's stability as phenoxide ion. By releasing H+ ion it will form stable C6H5O- ion. The groups having +I, -I , +M , -M efffects present on phenol will effect acidic nature of phenol. As +I or +M groups which are present at ortho and at para psitions will decrease the acidic character of phenol. If they are at meta position effect is less than at para or ortho positions.Similar to this -I or -M gorups are substituted on phenol they will increase the acidic nature. so, we can say that as the stability of phenoxide ion increases acidic nature of phenol also increases.Phenol can act as an acid due to it's stability as phenoxide ion. By releasing H+ ion it will form stable C6H5O- ion. The groups having +I, -I , +M , -M efffects present on phenol will effect acidic nature of phenol. As +I or +M groups which are present at ortho and at para psitions will decrease the acidic character of phenol. If they are at meta position effect is less than at para or ortho positions.Similar to this -I or -M gorups are substituted on phenol they will increase the acidic nature. so, we can say that as the stability of phenoxide ion increases acidic nature of phenol also increases.Phenol is a weak acid because of the presence of the hydrogen ions.
Why phenol does not dissolve in water when excess?
Phenol is slightly soluble in water due to hydrogen bonding between the hydroxyl group of phenol and water molecules. However, when excess phenol is added, it disrupts the hydrogen bonding network of water molecules, making it less soluble. This is because phenol-phenol interactions become stronger than phenol-water interactions, leading to precipitation.
Which is stronger acid ethanol or phenol?
Phenol is stronger acid than ethanol. Phenol's acidic strength stems from the presence of the -OH group attached directly to the aromatic ring, which allows it to readily donate a proton. Ethanol, in contrast, has a less acidic -OH group due to its aliphatic structure.
