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pH = 4 is about in the middle (4.7) of the values pH=pKa,1 and pH=pKa,2.

This is an indication of H2PO4- abundantly being present, because

  1. at pH=2.14 it is halfway forming its conjugate acid H3PO4

    and

  2. at pH=7.21 it is halfway forming its conjugate base HPO42-
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Q: Phosphoric acid H3PO4 has three dissociable protons with pkas 2.14 and 6.86 and 12.4 which form of the acid predominates in a solution of pH 4?
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