For a redox reaction to be spontaneous, the standard cell potential (cell) must be positive.
A positive sum of the two half-reactions' standard potentials
. The reaction will be spontaneous.
The sum of the voltages of the half-reactions is positive.
The element with the greater reduction potential is the one that is reduced.
The overall voltage for the non-spontaneous redox reaction between Mg and Cu can be calculated by finding the difference in standard reduction potentials between the two half-reactions. The standard reduction potentials for Mg and Cu are -2.37 V and 0.34 V, respectively. Therefore, the overall voltage would be (-2.37 V) - (0.34 V) = -2.71 V.
A positive sum of the two half-reactions' standard potentials
. The reaction will be spontaneous.
A spontaneous redox reaction is identified by a positive cell potential (E°) when measured under standard conditions, indicating that the reaction can occur without external energy input. This is often determined using the standard reduction potentials of the half-reactions involved; if the total cell potential is positive, the reaction is spontaneous. Additionally, spontaneity can be inferred from the Gibbs free energy change (ΔG), where a negative ΔG signifies that the reaction is thermodynamically favorable.
The reduction potential plus oxidation potential is negative.
A redox reaction with a positive standard electrode potential indicates that the reaction is spontaneous under standard conditions. This means that the tendency for the reduction half-reaction to occur is favored, making it more likely for the oxidizing agent to gain electrons. In practical terms, such reactions can drive processes like electrochemical cells, where energy is harnessed from the spontaneous electron transfer. Thus, a positive potential signifies a favorable thermodynamic outcome for the reaction.
If the standard reduction potential of a half-cell is positive, it indicates that the half-cell reaction is more favorable than the reduction of hydrogen ions to hydrogen gas at the standard hydrogen electrode (SHE). Therefore, when paired with the SHE, the half-cell reaction will proceed spontaneously in the forward direction, meaning that the half-cell will act as a cathode while the SHE acts as an anode. This results in the overall redox reaction being spontaneous.
The sum of the voltages of the half-reactions is positive.
A redox reaction will not be spontaneous if the standard cell potential (E°) is negative, indicating that the reaction favors the reactants rather than the products. Additionally, high activation energy barriers, unfavorable temperature conditions, or the presence of competing reactions can also hinder spontaneity. In such cases, external energy input may be required to drive the reaction forward.
A redox reaction is spontaneous when the overall change in Gibbs free energy (ΔG) is negative. This typically occurs when the standard electrode potentials of the half-reactions involved indicate a favorable direction for electron flow, resulting in a positive cell potential (E°). In simpler terms, a spontaneous redox reaction can occur without external energy input, driven by the inherent chemical properties of the reactants.
spontaneous redox reaction
The element with the greater reduction potential is the one that is reduced.
The element with the greater reduction potential is the one that is reduced.