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There are several simple tests for identifying Iron(II) ions, which can be carried out even in an elementary chemistry laboratory.

  • Add some ammonia solution to the testing solution, if Fe2+ present, there will be a green precipitate; Fe(OH)2.
  • Add some ammonium sulphide to the testing solution, if Fe2+ present, FeS would be observed as a black precipitate.
  • To the given solution, add a few milliliters from a K4[Fe(CN)6] solution, a Prussian blue solution or precipitate indicates that there is Fe2+ present.
  • To the given solution, add a few milliliters from a K3[Fe(CN)6] solution, a white precipitate indicates that there is Fe2+ present. (If the Prussian blue solution or precipitate is observed in this instance, there is Fe3+ present in the solution).
  • To the given solution, add a solution of ammonium thiocyanate. There will be no chemical change in this instance. Now add few drops of concentrated nitric acid and warm the solution. A deep red colour, (actually the colour intensity depends on the quantity of ammonium thiocyanate added) depicts that there is Fe2+ in the solution.

The related link below is posted to observe the contrasts between identifying Iron (II) ions and Iron (III) ions.

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What was the color produced when ferrous ion reacted with potassium ferricyanide?

The color produced when ferrous ion reacts with potassium ferricyanide is a deep blue color. This reaction is commonly used in chemical tests to detect the presence of ferrous ions in a solution.


How metallic hydroxide is form when an iron immerse in an acidic solution?

When iron is immersed in an acidic solution, it can react with the hydrogen ions from the acid to form ferrous ions (Fe2+). These ferrous ions can then react with hydroxide ions (OH-) in the solution to form iron(II) hydroxide (Fe(OH)2), which is a metallic hydroxide compound.


Why should only freshly prepared solution of ferrous sulphate solution be used?

Freshly prepared solution of ferrous sulfate should be used because it is prone to oxidation when exposed to air, leading to the formation of ferric ions. This can result in inaccurate test results due to the presence of ferric ions instead of ferrous ions. Additionally, solutions that have been stored for extended periods of time may also be contaminated with impurities, affecting their effectiveness.


Why potassium dichromate solution changes to green colour when it is added to ferrous ammonium sulphate solution?

The green color is due to the formation of chromium(III) ion, Cr3+, from the reduction of chromium(VI) ion, Cr2O72-. This reduction is caused by the ferrous ions in the ferrous ammonium sulfate solution, which get oxidized to ferric ions in the process. The overall reaction involves a transfer of electrons from the iron(II) ions to the chromium(VI) ions, resulting in the observed color change.


Why it is recommended to prepare ferrous ammonium sulfate solution in acidic medium?

Ferrous ammonium sulfate is prone to oxidation, forming insoluble iron hydroxides. Preparing the solution in an acidic medium helps to prevent oxidation of ferrous ions to ferric ions, ensuring the stability of the solution and enhancing its accuracy for titrations or other analytical procedures. Additionally, the acidic medium helps to maintain the solubility of the compound.

Related Questions

What was the color produced when ferrous ion reacted with potassium ferricyanide?

The color produced when ferrous ion reacts with potassium ferricyanide is a deep blue color. This reaction is commonly used in chemical tests to detect the presence of ferrous ions in a solution.


How metallic hydroxide is form when an iron immerse in an acidic solution?

When iron is immersed in an acidic solution, it can react with the hydrogen ions from the acid to form ferrous ions (Fe2+). These ferrous ions can then react with hydroxide ions (OH-) in the solution to form iron(II) hydroxide (Fe(OH)2), which is a metallic hydroxide compound.


Why alkaline solution containing ferrous ions is boiled during detection of nitrogen?

To convert ferrous ions to ferric as Fe2(SO4)3 .which then react with sodium ferrocyanide to give prussian blue colour.


What colored coating is formed on adding zinc granules to freshly prepared ferrous sulphate solution?

A red-brown colored coating is formed on adding zinc granules to freshly prepared ferrous sulphate solution. This is due to the oxidation of ferrous ions in the solution to ferric ions, which results in the formation of ferric oxide/hydroxide on the surface of the zinc granules.


Why should only freshly prepared solution of ferrous sulphate solution be used?

Freshly prepared solution of ferrous sulfate should be used because it is prone to oxidation when exposed to air, leading to the formation of ferric ions. This can result in inaccurate test results due to the presence of ferric ions instead of ferrous ions. Additionally, solutions that have been stored for extended periods of time may also be contaminated with impurities, affecting their effectiveness.


Why you use freshly prepared ferrous sulphate solution in detection of nitrogen?

Because in FeSO4, iron present in +2 oxidation state but the stable oxidation state is +3. The Fe(II) get oxidized into Fe(III) in ferrous sulfate solution that's why preparation of solution must necessary.


Why potassium dichromate solution changes to green colour when it is added to ferrous ammonium sulphate solution?

The green color is due to the formation of chromium(III) ion, Cr3+, from the reduction of chromium(VI) ion, Cr2O72-. This reduction is caused by the ferrous ions in the ferrous ammonium sulfate solution, which get oxidized to ferric ions in the process. The overall reaction involves a transfer of electrons from the iron(II) ions to the chromium(VI) ions, resulting in the observed color change.


If ferrous solution is stabilized with one molar sulfuric acid does that mean ferrous concentration is one molar?

Not necessarily or even usually. The term "one molar" refers to the concentration of the acid added and does not have anything to do with the concentration of ferrous ions.


Why it is recommended to prepare ferrous ammonium sulfate solution in acidic medium?

Ferrous ammonium sulfate is prone to oxidation, forming insoluble iron hydroxides. Preparing the solution in an acidic medium helps to prevent oxidation of ferrous ions to ferric ions, ensuring the stability of the solution and enhancing its accuracy for titrations or other analytical procedures. Additionally, the acidic medium helps to maintain the solubility of the compound.


Why do you add zinc metal during titration of ferrous oxalate and potassium permangnate?

Zinc metal is added during the titration of ferrous oxalate and potassium permanganate to ensure that all the permanganate ions are used to oxidize the ferrous ions and not any other substances present in the solution. The zinc reduces any excess permanganate ions to colorless Mn2+ ions, allowing for a more accurate determination of the endpoint of the titration.


What is a ferrous ion level?

A ferrous ion level refers to the concentration of iron in the body in its reduced, or ferrous, state. This measurement is often used to assess iron status and can be evaluated through blood tests. Abnormal levels of ferrous ions can indicate conditions such as iron deficiency or iron overload.


How do you remove and identify salt?

From solution I expect you mean. The really quickest way is to evaporate the solution off, and thus it will leave the salt crystals behind. From this tests can be carried out to see what salt it is, these are tests for ions. Such tests include a flame test. If the flame changes to yellow when the compound is burnt then it suggests the precense of sodium ions, lilac for potassium ions and so on. You could also do a precipitation aswell as a test for chloride ions ect.