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Spectator ions, in a chemical reaction, are ions that don't take part in the overall reaction. For instance, consider the following reaction:

Pb2+ (aq) + 2 NO3 (aq) + 2 K+(aq) + 2 I-(aq) ---> PbI2(s) + 2 K+(aq) + 2 NO3-(aq)

The bolded and italicized compounds are spectator ions. They do not play an active role in the reaction. So, when these spectator ions are removed, we end up with a net ionic equation:

Pb2+(aq) + 2 I-(aq) ---> PbI2(s)

Source: College student in Chemistry, wrote these examples out of the book.

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