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As you know that hydrogen bonding aids the formation of the secondary structures. Once these structures are formed (ie alpha helix, beta-sheet, beta-turn), the R groups now can interact with other R groups. In the tertiary structure, the weak interactions (ie hydrogen bonding, ionic bonding, van der waals interactions) aid in the 3D structure of the protein. Disulfide bonds form in the tertiary structure which add extra stability to the overall 3D shape of the protein.

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