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Le Chatelier's principle essentially states that if a stress is imposed on a system at equilibrium, the equilibrium will shift to minimize the stress.

These stresses include:

-Change in temperature

-Change in pressure/volume (for gases)

-Change in concentration

A simple example of this:

N2(g) + 3 H2(g) ⇌ 2 NH3(g) ΔH = −92kJ/mol

-If you add N2(g) or 3 H2(g) the equilibrium will shift to the right (to the products), and more NH3(g) will be created so as to minimize the stress.

- If you add NH3(g), the equilibrium will shift to the left (to the reactants), and more N2(g) and H2(g) will be created.

-If you increase the temperature, the equilibrium will shift to the left (to the reactants). The reason for this is that the above reaction is exothermic, and releases heat. Consequently, the heat is on the side of the products, and thus if you add heat, the equilibrium will shift to the reactants and more N2(g) and H2(g) will be created.

- If you increased the pressure, which is the same as decreasing the volume, the reaction will shift to the side with fewer moles, which, in this case, is the products. Thus, more NH3(g) will be created.

-Conversely, if you decrease the pressure (increase the volume), the reaction will shift to the side with a greater number of moles, which, in this case, is the reactants. Thus, more N2(g) and H2(g) will be created.

*It is important to note that changing pressure and volume only effects the equilibrium in gaseous reactions!

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