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Evaporation is the release of energy from water in the case of an inequality of energy between water body and surroundings.

Thermodynamics dictate energy will seek an equilibrium. When a liquid has a significantly high enough energy difference from its surroundings, the energy leaves the water by pulling the warmer molecules from the surface. If this happens in an enclosed space, the water vapour, after evaporating, cools and falls back to join the water.

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