alkali earth , alkali,transational and other elements including C,S,As etc
Potassium ions produce a lilac flame in a flame emission photometer. The presence of potassium in a sample can be detected by observing this characteristic color emission when the sample is introduced into the flame.
Advantages of flame emission include high sensitivity, wide dynamic range, and speed of analysis. However, disadvantages can include interferences from other elements, the need for sample preparation, and potential contamination of the flame.
Different elements have different emission spectra, meaning that if the electrons in an atom are excited, they will release that energy in different color of light. The flame color depends on the elements in the compound.
The emission spectrum of an element
For one thing, atomic absorption equipment is basically a fancier version of flame emission equipment (I'm unaware of any instrument capable of doing AA that can't also do FE), and flame emission doesn't require you to change tubes every time you want to check for another element.
Potassium ions produce a lilac flame in a flame emission photometer. The presence of potassium in a sample can be detected by observing this characteristic color emission when the sample is introduced into the flame.
Examples: emission spectrometry, flame photometry, atomic absorption, etc.
Flame photometry can be used for the measurement of elements which can easily be excited like Ca, K, Na, Ba, Cu etc. However due to low temperature of flame the elements like Fe can not be excited and hence not measured using Flame photometry.
Advantages of flame emission include high sensitivity, wide dynamic range, and speed of analysis. However, disadvantages can include interferences from other elements, the need for sample preparation, and potential contamination of the flame.
One method more advanced than a flame test is mass spectrometry. In mass spectrometry, the sample is ionized and the resulting ions are separated based on their mass-to-charge ratio. This allows for precise identification of elements and isotopes present in the sample.
Chemical interference occurs due to the absorbance/emission by molecules that did not break down into atoms. Inductively-coupled plasma mass spectrometry has less chemical interference as its hotter temperature breaks down everything into atoms.
Different elements have different emission spectra, meaning that if the electrons in an atom are excited, they will release that energy in different color of light. The flame color depends on the elements in the compound.
Answer- Flames in atomic emission are more sensitive to flame instability because optimum excitation conditions vary widely from element to element. High temperatures are needed for excitation of some elements and low temperatures for others. The region of flame that gives rise to optimum line intensities varies from element to element. Flame is rarely use in atomic emission because atomization is more complete when using a plasma due to the production of high temperatures. Also the plasma helps reduce the ionization interference effects. In flame absorption, after the sample is nebulized by a flow of gaseous oxidant, mixed with a gaseous fuel and carried into the flame it is then atomized. Then some of the atoms in the gas ionize to form cations and electrons. In flame emission the sample is introduce with argon, carries the sample into the flame. The flame is suppose to atomize the sample, while the flow of gas takes the ions and electrons to be detected.
The emission spectrum of an element
For one thing, atomic absorption equipment is basically a fancier version of flame emission equipment (I'm unaware of any instrument capable of doing AA that can't also do FE), and flame emission doesn't require you to change tubes every time you want to check for another element.
Potassium ions produce a lilac or light pink flame when using a flame emission photometer. The color is distinct and helps to identify the presence of potassium in a sample based on the emission spectrum produced when the sample is exposed to heat in the flame.
Lithium and calcium ions typically produce the least easily identified colors in a flame test. Their emission colors are often faint and less distinct compared to other elements.