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Equatorial atoms are the atoms in a three dimensional model that are on the x-y axis.

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What is the bond angle formed by an axial atom the central atom and any equatorial atom?

The bond angle formed by an axial atom, the central atom, and an equatorial atom in a trigonal bipyramidal molecular geometry is approximately 90 degrees.


Why is the most stable conformational isomer of cis-1-bromo-2-chlorocyclohexane bromine equatorial and chlorine axial instead of bromine axial and chlorine equatorial?

The most stable conformation has the larger bromine atom in the equatorial position to reduce steric hindrance caused by its size. Placing the smaller chlorine atom in the axial position minimizes the overall energy of the molecule due to the difference in size between bromine and chlorine. This arrangement follows the principles of minimizing steric hindrance and maximizing stability.


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