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It's a Trigonal-Bipyrimidal

So, P is the central atom, while the Cl and F atoms surround it :)

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What is the hybridization of pcl3f2?

The hybridization of PCl3F2 is sp3d. This hybridization occurs when there are five electron domains around the central atom (phosphorus), consisting of three bonding pairs and two lone pairs.


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In PCl3F2, both fluorine atoms are positioned in the axial positions of the trigonal bipyramidal molecular geometry due to their higher electronegativity compared to chlorine. This arrangement minimizes steric repulsion, as the larger chlorine atoms occupy the equatorial positions, where they have more space. The axial positions are also less crowded, allowing for a more stable configuration. Thus, placing the more electronegative fluorine atoms axially helps achieve a lower energy state for the molecule.


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