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In PCl3F2, both fluorine atoms are positioned in the axial positions of the trigonal bipyramidal molecular geometry due to their higher electronegativity compared to chlorine. This arrangement minimizes steric repulsion, as the larger chlorine atoms occupy the equatorial positions, where they have more space. The axial positions are also less crowded, allowing for a more stable configuration. Thus, placing the more electronegative fluorine atoms axially helps achieve a lower energy state for the molecule.

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10h ago

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