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An electrode is an electric conductor, usually metals. A Cu electrode means copper electrode.

In a voltaic Zn-Cu cell, or battery, (a spontaneous reaction, so the voltage is always positive) it consists of two electrodes in which each of them is immersed in their designated electrolytic solution. When the spontaneous reaction occurs, electrons get attracted to the cathode and make it negatively charged. Meanwhile, electrons get farther from the anode, making it positively charged.

cathode=positive

anode=negative

how do you identify which is anode/cathode?

Zn2+ + 2e- --> Zn(s) // V=-0.76

Cu2+ + 2e- --> Cu(s) // V=+0.34

A cathode is the electrode with which the reduction, or gaining of electrons, takes place. Whichever has the higher potential to gain electrons will serve as a cathode. The more positively charged an atom is, then the more it is likely to attract electrons.

In this case, the cathode is the copper.

Anode is the opposite of cathode.

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