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PO3-3 does not exist in solution or normal ionic compounds (I cannot rule out exotic compounds). It is the analog to phosphate. "-ites" generally have one less O atom and the same charge as the "-ates". However, phosphate (PO4-3)and carbonate (CO3-2) do not have corresponding "-ites". Applying base to H3PO3 only removes 2 Hydrogens to give the HPO3-2 ion which is called (confusingly) phosphite; the remaining H is bound to the P (p. 512, "Advanced Inorganic Chemistry" by F. A. Cotton, Interscience, NY1966).


Dr. Bob Butler
Chemistry Lecturer
Baruch College, NY, NY
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