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Some ligands such as acetyl acetonato, glycine etc. have both neutral donor and anionic (acidic) groups. Co-ordination number and oxidation state i.e., charge on metal ion gets satisfied simultaneously when metal ions are co-ordinated to such ligands. Complexes so formed are called inner metallic complexes or only inner complex. Examples of inner complexes are:

[Co3(gly)3], [Co(acac)3], [Cu(gly)2] and [Cu(big)2]

whre, gly = glycinato, acac = acetyl acetanato and big = biguanido.

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