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What is normality of a solution?

Updated: 8/11/2023
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13y ago

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In chemistry, the normality of a solution is defined as the molar concentration ci divided by an equivalence factor feq:

normality = M / feq

The equivalence factor feq is the factor of how many moles of a reactant is needed to give 1 mole of reactive entities, like:

  • protons (H+ or OH-) in acid/base reactions,
  • electrons (e-) in redox reactions and
  • ion charges in ionic salt precipitation reactions

Examples:

Ca(OH)2 feq = 1/2 = 0.5

NH3 feq = 1 (accepting 1 proton as base, not 3!)

H3PO4 feq = 1/3 = 0.333..3 (donating 3 protons with strong acid)

H2C2O4.2H2O (oxalic acid, standard) feq = 0.5 (both as bacid and as reductant)

Na2S2O3 (thio) feq = 1 (donating 1 electron)

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12y ago
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13y ago

It gives you 'how many' moles of unified/equivalent reacting particles (mostly protons for acid/base reactions or electrons for redox reactions) there are within one mole of compound considered.

Examples:

In acidimetry

oxalic acid (COOH)2 is diprotic (2H+), so two equivalents per mole: 1.0 M = 2.0 N

HPO42- + 2H+ --> H3PO4 is 2 equiv. per mol with strong acid

HPO42- + OH- --> PO43- + H2O is 1 equiv. per mol with strong base

In oxidimetry

oxalic acid (COOH)2 is di-electrovalent (2e-), so also two equivalents per mole: 1.0 M = 2.0 N

MnO4- + 8H+ + 5e- --> Mn2+ + 4H2O is 5 equiv. per mol (in strong acid solution)

MnO4- + 2H2O + 3e- --> MnO2 + 4OH- is 3 equiv. per mol (in neutral solution)

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11y ago

number of moles divided on volume in liter

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