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Just replace one H and add a Cl (CH3Cl). In the next step replace another H by Cl. It's a chain reaction under sunlight: CH4+Cl2=CH3Cl+HCl CH3Cl+Cl2=CHCl2+HCL CH2Cl+Cl2=CHCl3+HCl CHCl3+Cl2=CCl4+HCl I'm sure now the structural formula will be apiece of cake.

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