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Ozone is commonly produced when Nitrogen Oxides, Carbon Monoxide, VOC's (Volatile Organic Compounds) react in the presence of sunlight. In the simplest terms Ozone is formed by an atomic oxygen atom synthesizing with a diatomic oxygen molecule and a third molecule M acting as a stabilizer to take away excess energy. However when explaining the series of reactions that take place in the formation of Ozone almost always you will find that the reaction is initiated by various VOC's or Carbon Monoxide reacting with the Hydroxyl radical; this is followed by the conversion of Nitrogen Oxide into Nitrogen Dioxide, then the photolysis of Nitrogen Dioxide to produce atomic Oxygen, which in turn combines with diatomic Oxygen to produce Ozone.

The following reaction is initiated by Carbon Monoxide:

OH + CO--> H + CO2(A Hydrogen atom is formed by the reaction of Carbon Monoxide and the Hydroxyl radical)

H + O2 -->HO2 (In turn the Hydrogen atom reacts with the surrounding oxygen to produce the Peroxy radical HO2)

HO2 + NO--> OH + NO2(Peroxy radical HO2 reacts with Nitrogen Oxide to produce Nitrogen Dioxide)

NO2+ hv (wavelengths 200-420 NM)--> NO + O (Nitrogen Dioxide is photolysed, photo-Dissociated back into Nitrogen oxide, and produced Atomic Oxygen)

O2 + O + M --> O3 + M (atomic oxygen formed in the previous reaction reacts with Oxygen and the stabilizer molecule M)

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O2 + .O. -> O3

A molecule of oxygen with a oxygen free radical (that has 2 unpaired electrons), makes an ozone molecule.

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