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According to the Wikipedia article on toluene, its melting point is -95 degrees C, and its boiling point is 110.6 degrees C.

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Why does benzene have a lower boiling point but a much higher melting point than toluene?

Benzene has a lower boiling point than toluene because it has a symmetric structure that experiences weaker van der Waals forces, making it easier for benzene molecules to separate and vaporize. The higher melting point of benzene compared to toluene is due to the presence of delocalized electron cloud in benzene, which results in stronger intermolecular interactions (π-π interactions) between benzene molecules in the solid state.


Why is it that aniline has a high boiling point to phenol and phenol has a high boiling point than toluene and toluene has a high boiling point than benzene?

Aniline has a higher boiling point than phenol because aniline can form strong hydrogen bonds due to the presence of an amino group. Phenol has a higher boiling point than toluene because phenol molecules can form intermolecular hydrogen bonds because of the hydroxyl group. Toluene has a higher boiling point than benzene due to the presence of a bulky methyl group which increases Van der Waals forces between toluene molecules.


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