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as far as i know the B.Pt. is defined as " when the vopour pressure of the liquid is equal to the atomospheric pressure then it is said to be the boiling point of the liquid." similarly "when the vapuor pressure of the solid is equal to atmospheric pressure then its corresponding temperature is called melting point of that compound." so a compound may be a low melting one but the same compound may be ahigh boiling liquid. this is due to the inter & intra molecular forces that exists in the molecules. so there is no specific equation that a compound having a m.p. of 102c will have a b.pt. of some particular value.

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