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The s orbital is present in all valid principal quantum number shells.
The p orbital is present in n = 2 and higher.
The d orbital is present in n = 3 and higher.
The f orbital is present in n = 4 and higher.

So the invalid ones are b (there are no 2d orbitals) and c (there are no 3f orbitals). 4s and 3p are perfectly legitimate.

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Q: Which of these orbital designations are invalid a. 4s b. 2d c. 3f d. 3p?
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