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Van Vleck paramagnetism theory (VBT) is limited in explaining the paramagnetic behavior of oxygen because it does not take into account the role of electron-electron repulsions and the need for molecular orbital theory to properly describe the bonding in molecules like oxygen. Oxygen exhibits paramagnetism due to the presence of unpaired electrons in its molecular orbitals, which VBT fails to adequately account for. Molecular orbital theory, which considers the delocalization of electrons in molecular orbitals, provides a more comprehensive explanation for the paramagnetic behavior of oxygen.

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1y ago

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