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Hcl is a strong acid. NaCl is formed by the reaction of Hcl and any base .But NaCl is not a covalent compound and it exists as Na+ and Cl-.Na+and OH- cannot react with EachOther in Aqueous solutions as as the are formed in aqueous solutions and they behave like ions . hence neither H+ nor OH- is consumed by this mixture whereas acetic acid and acetate ions can consume small amt of these ions.Hence the mix. act as buffer

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Q: Why a mixture of ch3cooh and ch3cooNa can act as a buffer?
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