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Lithium and beryllium have a high charge to size ratio-- because the ions are so small. These small ions polarise the electron clouds of other ions distorting them and giving the bond covalent character- (Fajan's Rules). Lithium "salts" tend to be more soluble in organic polar solvents than the other alkali metal salts.

Beryllium, as Be2+ would be the most polirising ion of all- for example the chloride has a peculiar chain structure indicating covalency.

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