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Why color of potassium permanganate disappear slowly first but quite fast afterwards in titration?
The color of potassium permanganate disappears slowly at first because it is being consumed by the reaction with the analyte in small increments. Once most of the analyte has reacted, the color disappears faster because there are fewer molecules left to react with. This leads to a more rapid consumption of the remaining permanganate ions.
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Why does HCl not used to acidify the media in potassium permanganate titration?
HCl is not used to acidify the media in potassium permanganate titration because it can react with potassium permanganate, which can interfere with the titration results. Sulfuric acid is usually preferred as it does not react with potassium permanganate and ensures accurate titration results.
Why potassium permanganate is used as a self indicator in the titration of oxalic acid?
Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.
Why is HCl not used as catalyst in the standardization of potassium permanganate?
HCl is not used as a catalyst in the standardization of potassium permanganate because it can react with permanganate ions, affecting the accuracy of the titration. The standardization process requires a neutral or slightly basic medium to ensure the permanganate titration proceeds correctly.
What type of indicator is used during potassium permanganate titration?
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
How do you determine the end point of titration involving sodium oxalate and potassium permanganate?
The end point of the titration is typically determined by observing a color change. In the case of sodium oxalate and potassium permanganate, the permanganate ion is a deep purple color, and it will turn colorless once it has reacted completely with the oxalate ion. This color change indicates the end point of the titration.
Why does HCl not used to acidify the media in potassium permanganate titration?
HCl is not used to acidify the media in potassium permanganate titration because it can react with potassium permanganate, which can interfere with the titration results. Sulfuric acid is usually preferred as it does not react with potassium permanganate and ensures accurate titration results.
Why potassium permanganate is used as a self indicator in the titration of oxalic acid?
Potassium permanganate is used as a self-indicator in the titration of oxalic acid because the initial pink color of potassium permanganate is decolorized in the presence of oxalic acid due to its reducing properties. The endpoint of the titration is reached when all the oxalic acid has reacted with the potassium permanganate, causing the pink color to persist. This change in color helps in determining the equivalence point of the titration.
Why is HCl not used as catalyst in the standardization of potassium permanganate?
HCl is not used as a catalyst in the standardization of potassium permanganate because it can react with permanganate ions, affecting the accuracy of the titration. The standardization process requires a neutral or slightly basic medium to ensure the permanganate titration proceeds correctly.
What type of indicator is used during potassium permanganate titration?
Usually there is no indicator needed in potassium permanganate titrations as there will be an excess of manganate ions in the conical flask, turning the solution from colourless to pale pink.
How do you determine the end point of titration involving sodium oxalate and potassium permanganate?
The end point of the titration is typically determined by observing a color change. In the case of sodium oxalate and potassium permanganate, the permanganate ion is a deep purple color, and it will turn colorless once it has reacted completely with the oxalate ion. This color change indicates the end point of the titration.
Why no use indicator in the standardizing potassium permanganate titration?
In the standardization of potassium permanganate titration, an indicator is not used because the titration is self-indicating. This means the solution being titrated changes color at the end point, so an additional indicator is not necessary. It is important to carefully observe the color change to ensure accurate titration results.
How do you redox titration by Potassium Permanganate?
In a redox titration using potassium permanganate, the permanganate ion (MnO4-) acts as the oxidizing agent while the other substance being titrated acts as the reducing agent. The endpoint is reached when all the reducing agent has been consumed, leading to a color change from purple to colorless or light pink. The volume of potassium permanganate solution required to reach the endpoint is used to calculate the concentration of the reducing agent.
Why do you add zinc metal during titration of ferrous oxalate and potassium permangnate?
Zinc metal is added during the titration of ferrous oxalate and potassium permanganate to ensure that all the permanganate ions are used to oxidize the ferrous ions and not any other substances present in the solution. The zinc reduces any excess permanganate ions to colorless Mn2+ ions, allowing for a more accurate determination of the endpoint of the titration.
Why you use dilute H2SO4 in titration permanganat and oxalic acid?
Dilute sulfuric acid is used in the titration of potassium permanganate with oxalic acid because it helps to maintain a stable pH and prevents the oxidation of oxalic acid by permanganate ions. This ensures accurate results by minimizing side reactions and interference.
How is oxalic acid vs NaOH titration different from oxalic acid vs potassium permegnate titration?
In the titration of oxalic acid with NaOH, the acid-base reaction involves the neutralization of the acid by the base. However, in the titration of oxalic acid with potassium permanganate, the permanganate ion oxidizes the oxalic acid to carbon dioxide. This difference in reaction mechanisms leads to different equivalence points and color changes in the two titrations.
What is the mechanism of the redox reaction between potassium permanganate and hydrogen peroxide?
The redox reaction between potassium permanganate and hydrogen peroxide involves the transfer of electrons. In this reaction, potassium permanganate acts as an oxidizing agent, while hydrogen peroxide acts as a reducing agent. The permanganate ion (MnO4-) is reduced to manganese dioxide (MnO2), while hydrogen peroxide is oxidized to water and oxygen gas. This reaction occurs in an acidic solution and is often used as a titration method in analytical chemistry.
Why titration of potassium permanganate is carried out in acidic medium?
Potassium permanganate undergoes reduction in acidic medium which generates a color change that can be easily observed, making it suitable for use as an oxidizing agent in titrations. Additionally, the acidic medium prevents the premature reaction of permanganate ions with reducing agents present in the solution before the titration is conducted.
