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Lipids don't have the same number of carbon atoms as glucose -- glucose has six while a lipid triglyceride can have a number exceeding 60 carbons. The reason it makes more ATP than glucose is because there are more chemical bonds to be broken as they are relatively large molecules.

Energy is stored in covalent bonds when they are formed, and is released when they are broken. The release of energy can be used to bind a phosphate (Pi) to a molecule of ADP (adenosine diphosphate, with two phosphate groups), creating ATP (adenosine triphosphate, with three phosphates). The greater number of bonds in the molecule, the greater amount of energy released, so more ATP can be synthesized.

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Q: Why do lipid produce more ATP than glucose even though they have same number of carbon?
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