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It is a matter of lattice energy vs. heat of solution. The lattice energy is the energy change associated with the ions in the gas phase forming a solid (crystalline) lattice. It is typically an exothermic process, liberating energy. The heat of solution is the energy change associated with the ions being dissolved by solvent, and can be exothermic or endothermic. If the heat of solution is more exothermic than the lattice energy, than it is energetically favorable for the ionic compound to be solvated. If the lattice energy is more exothermic, than solvation will not occur.

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