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Many metal ions (eg. Ca and Mg) only react completely when EDTA is in pure anionic form (EDTA)4- anion. Since it is a quadruple acid this can only be realized at pH value above 10 for Ca2+ ions, for Mg2+ even higher: >12

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Why is the pH of the medium important in edta titration?

The pH of the medium is important in EDTA titration because the formation of the metal-EDTA complex depends on the pH. At certain pH levels, the metal-EDTA complex formation is optimized, leading to accurate results. Deviations from the optimal pH can affect the stability of the complex and lead to incorrect titration results.


Why is phenolphthalein indicator not used in EDTA titration?

Phenolphthalein is not suitable for use in EDTA titration because it changes color at a pH range that is much lower than the pH range at which the EDTA-metal complex formation occurs. EDTA titration typically requires indicators that change color in a more acidic pH range.


Why you use pH 10 buffer in EDTA titration?

It is necessary to keep the pH at about 10 for two reasons: (a) all reactions between metal ions and EDTA are pH dependent, and for divalent ions, solutions must be kept basic (and buffered) for the reaction to go to completion; (b) the eriochrome black T indicator requires a pH of 8 to 10 for the desired color change.


Why you use pH 10 buffer in EDTA titration and the indicator paper not be put into the solution?

A pH 10 buffer is used in EDTA titrations to ensure that the reaction occurs at a consistent pH that is optimal for the formation of metal-EDTA complexes. The indicator paper is not added to the solution because the color change of the metal-EDTA complex is independent of pH and will occur naturally when all the metal ions are chelated by the EDTA.


Why you have to add buffer before titration with EDTA?

Adding a buffer solution before titration with EDTA helps to maintain a constant pH which is crucial for the formation of metal-EDTA complexes. The buffer solution prevents any fluctuations in pH that could affect the accuracy and precision of the titration results.

Related Questions

Why is the pH of the medium important in edta titration?

The pH of the medium is important in EDTA titration because the formation of the metal-EDTA complex depends on the pH. At certain pH levels, the metal-EDTA complex formation is optimized, leading to accurate results. Deviations from the optimal pH can affect the stability of the complex and lead to incorrect titration results.


Why you use pH 10 buffer in EDTA titrtion?

A pH 10 buffer is used in EDTA titration because it ensures that the metal ions being titrated remain in their complexed form with EDTA, which has higher stability at alkaline pH. This helps in achieving accurate and precise results in the titration process.


Why is phenolphthalein indicator not used in EDTA titration?

Phenolphthalein is not suitable for use in EDTA titration because it changes color at a pH range that is much lower than the pH range at which the EDTA-metal complex formation occurs. EDTA titration typically requires indicators that change color in a more acidic pH range.


What is the need for an ammonical buffer solution in the determination of hardness of water by edta titration?

during the complexometric titration using edta it is very necessary to maintain the ph of the solution near about 10 so we use ammonium chloride buffer if we will not use this buffer dring the titration ph of sol. will ho lower side


Why you use pH 10 buffer in EDTA titration?

It is necessary to keep the pH at about 10 for two reasons: (a) all reactions between metal ions and EDTA are pH dependent, and for divalent ions, solutions must be kept basic (and buffered) for the reaction to go to completion; (b) the eriochrome black T indicator requires a pH of 8 to 10 for the desired color change.


Why you use pH 10 buffer in EDTA titration and the indicator paper not be put into the solution?

A pH 10 buffer is used in EDTA titrations to ensure that the reaction occurs at a consistent pH that is optimal for the formation of metal-EDTA complexes. The indicator paper is not added to the solution because the color change of the metal-EDTA complex is independent of pH and will occur naturally when all the metal ions are chelated by the EDTA.


Why you have to add buffer before titration with EDTA?

Adding a buffer solution before titration with EDTA helps to maintain a constant pH which is crucial for the formation of metal-EDTA complexes. The buffer solution prevents any fluctuations in pH that could affect the accuracy and precision of the titration results.


Why is a solution containing a metal ion buffered before titration with EDTA?

Buffering the solution containing a metal ion before titration with EDTA helps maintain a constant pH, which is crucial for the accuracy and precision of the titration. The buffering prevents large pH changes that could affect the formation of metal-EDTA complexes and lead to errors in the titration results.


How does EDTA and titration work?

EDTA is a chelating agent that binds to metal ions. In titration, EDTA is used to determine the concentration of metal ions in a solution by forming a complex with the metal ion. The endpoint of the titration is identified by a color change indicator or a pH meter, indicating that all metal ions have reacted with EDTA.


Why is the pH adjusted to 10 before the complexometric titration?

Adjusting the pH to 10 before complexometric titration helps ensure the formation of a stable metal-ligand complex. At pH 10, metal ions form strong complexes with the chelating agent (usually EDTA) without interference from other ions. This pH also helps maintain the reaction conditions constant and improves the accuracy of the titration results.


Why is NH3-NH4CL buffer preferred in edta titration for determination of mg?

The NH3-NH4Cl buffer is preferred in EDTA titration for the determination of magnesium because it helps maintain a relatively constant pH (around 10), which is necessary for the formation of stable complexes between EDTA and magnesium ions. The NH4Cl helps prevent the precipitation of magnesium hydroxide, which could interfere with the titration.


Why buffer solution must be used for titration with EDTA?

A buffer solution must be used for titration with EDTA because it helps maintain a constant pH during the titration process. EDTA forms complexes with metal ions at specific pH levels, so maintaining a steady pH ensures accurate and reproducible results. Additionally, a buffer solution helps prevent changes in the pH that could interfere with the formation of the metal-EDTA complexes.