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Why does chlorine have more electron affinity than fluorine although it is below fluorine in periodic table?
Generally electron affinity goes up as you go from left to right across the Periodic Table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine.
(Note that the most electronegative element is fluorine however; 'electronegativity' is not exactly the same as 'electron affinity'.)
Electronegativity is the ability of an atom in a molecule to draw bonding electrons to itself
Electron affinity is a measure of the energy change when an electron is added to a neutral atom to form a negative ion.
The reason that the electron affinity is not as high as might otherwise be predicted for fluorine, is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).
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Does Iodine have less electron affinity than fluorine?
Yes. It's true. Chlorine has the highest electron affinity, then Fluorine, Bromine and Iodine
Why the electron affinity of fluorine is less than that of chlorine?
Generally electron affinity goes up as you go from left to right across the Periodic Table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine (note that the most electronegative element is fluorine however).The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).Note that there are a number of other exceptions to the general rule of electron affinity increasing towards the upper right corner -- see the Related Questions links to the left for an explanation of some of those other exceptions.See also the Web Links to the left for more information about electron affinities and the fluorine-chlorine exception.
What elements has the largest electron affinity?
AnswerElectron affinity is the energy released when we add an electron to the outermost orbit of the atom. Halogens are the higher in electron affinity, and chlorine has the higher electron affinity than rest of the halogens. The irregularity in the electron affinity trend between Cl and F is due to the small size of the F atom. Although F definitely has a higher attraction for an electron than Cl (as evidenced by its high electro negativity value), the small size of the F atom means that adding an electron creates significant repulsion. Since electron affinity is an energy measurement, the total energy associated with electron affinity winds up being the energy that is released by the electron binding to the nucleus, minus the energy involved in overcoming the electrical repulsion in the outer shell.This makes the fluoride anion so formed unstable due to a very high charge/mass ratio. Also, fluorine has no d electrons which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
Which has a greater electron affinity fluorine or bromine?
Fluorine has greater electron affinity than bromine, or any other element.
How will you account for the fact that fluorine which has a higher electronegativity and a lower electron affinity than those of chlorine is a stronger oxidizing agent than chlorine?
Fluorine is a stronger oxidizing agent than chlorine because despite having a lower electron affinity, its smaller size and higher electronegativity allow it to attract electrons more strongly, making it more reactive. This stronger ability to attract electrons results in a higher tendency for fluorine to gain electrons and undergo reduction reactions, which characterizes it as a stronger oxidizing agent compared to chlorine.
Which has higher electron affinity fluorine or chlorine?
Fluorine has higher electron affinity than any other element.
Does Iodine have less electron affinity than fluorine?
Yes. It's true. Chlorine has the highest electron affinity, then Fluorine, Bromine and Iodine
Why would flurine have the highest electron affinity?
Fluorine has the highest electron affinity because it has a small atomic size and high effective nuclear charge, which results in a strong attraction between the nucleus and incoming electrons. This strong attraction allows fluorine to readily accept an additional electron and achieve a stable electron configuration.
Why the electron affinity of fluorine is less than that of chlorine?
Generally electron affinity goes up as you go from left to right across the Periodic Table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine (note that the most electronegative element is fluorine however).The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).Note that there are a number of other exceptions to the general rule of electron affinity increasing towards the upper right corner -- see the Related Questions links to the left for an explanation of some of those other exceptions.See also the Web Links to the left for more information about electron affinities and the fluorine-chlorine exception.
What elements has the largest electron affinity?
AnswerElectron affinity is the energy released when we add an electron to the outermost orbit of the atom. Halogens are the higher in electron affinity, and chlorine has the higher electron affinity than rest of the halogens. The irregularity in the electron affinity trend between Cl and F is due to the small size of the F atom. Although F definitely has a higher attraction for an electron than Cl (as evidenced by its high electro negativity value), the small size of the F atom means that adding an electron creates significant repulsion. Since electron affinity is an energy measurement, the total energy associated with electron affinity winds up being the energy that is released by the electron binding to the nucleus, minus the energy involved in overcoming the electrical repulsion in the outer shell.This makes the fluoride anion so formed unstable due to a very high charge/mass ratio. Also, fluorine has no d electrons which limits its atomic size. As a result, fluorine has an electron affinity less than that of chlorine.
Which has a greater electron affinity fluorine or bromine?
Fluorine has greater electron affinity than bromine, or any other element.
Halogen with the least-negative electron affinity?
The halogen with the least-negative electron affinity is astatine. Electron affinity and electronegativities decreases down a group. Since astatine is the last halogen located in Group 17 as you move down the column from fluorine, it has the least negative electron affinity.
How will you account for the fact that fluorine which has a higher electronegativity and a lower electron affinity than those of chlorine is a stronger oxidizing agent than chlorine?
Fluorine is a stronger oxidizing agent than chlorine because despite having a lower electron affinity, its smaller size and higher electronegativity allow it to attract electrons more strongly, making it more reactive. This stronger ability to attract electrons results in a higher tendency for fluorine to gain electrons and undergo reduction reactions, which characterizes it as a stronger oxidizing agent compared to chlorine.
Which has more electron affinity between cl2 and f2?
The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).
Which has lower electron affinity between oxygen and fluorine?
Fluorine has a lower electron affinity than oxygen. This is because fluorine already has a full outer shell of electrons and adding another electron would create repulsion due to electron-electron interactions. Oxygen, on the other hand, has space in its outer shell to accept an additional electron more easily.
Is electron affinity of N is greater than F?
No, it is not. Electron affinity follows a trend like electronegativity and hence increases as we move from left to right across a period. So, Fluorine has the highest electron affinity among 1st period elements.
Why EA of fluorine is less than chlorine?
Generally electron affinity goes up as you go from left to right across the periodic table, and decreases as you go down a column. However, fluorine is an exception -- and the element with the highest electron affinity is chlorine (note that the most electronegative element is fluorine however).The reason that the electron affinity is not as high as might otherwise be predicted for fluorine is that it is an extremely small atom, and so it's electron density is very high. Adding an additional electron is therefore not quite as favorable as for an element like chlorine where the electron density is slightly lower (due to electron-electron repulsion between the added electron and the other electrons in the electron cloud).Note that there are a number of other exceptions to the general rule of electron affinity increasing towards the upper right corner -- see the Related Questions links to the left for an explanation of some of those other exceptions.See also the Web Links to the left for more information about electron affinities and the fluorine-chlorine exception.
