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Because it corresponds to the filling of the 3s and 3p subshells (of the third shell) which take a total of 8 electrons, two in the 3s and 6 in the 3p subshell. Each additional electron in these sub shells represents a different element eg 1 electron, 3s1, corresponds to sodium, 3 electrons, 3s2, 3p1, correspond to aluminium, 7 electrons, 3s2, 3p5, to chlorine.

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