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Because of the mechanism of addition polymerization;

In addition polymerization the pi-bond of a molecule with a double bond (e.g. ethene) is broken by attatchment of a radical (a molecule with a lone electron) to the molecule with the double bond:

one of the two electrons that formed the double bond pairs up with the single electron from the radical so the other electron from the double bond becomes a lone electron himself; and so it continues until two radicals meet each other.

So you need to have a double bond in order to have this kind of polymerization;

(there are other kinds of polymerization of molecules whitch have a functional group but ethane nor ethene has these so it doesn't apply to them.)

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14y ago

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