-NH2 has a very good isomer effect that activates o,p
-NHCOCH3 has 2 isomers one who activates o,p and one who deactivates the o,p
salicytic acid is a ortho para directing group ....however check up on that ...i am not completely certain .. Actually, it is a meta-directing group, because of the carboxylic acid functional that the salicylic acid contains. Hope that was helpful.
orientation of incoming Nitro group is destined by already present group on benzene ring . if already present group is electron donating group, it will promote electron density at ortho and para position and , therefore, nitro group is formed on ortho and para position.
the ortho effect operates due to position of substituted group in ortho position. it increases the steric repulsion in 'amino' grup of aniline there by decreasing its basicity ,i.e tendency to accept proton.
The hydroxyl group (-OH) is an ortho para director in electrophilic aromatic substitution reactions because it is an activating group that stabilizes the developing positive charge on the ortho and para positions through resonance. This makes these positions more electron rich and therefore more susceptible to electrophilic attack.
Ortho-nitrobenzoic acid is more acidic than ortho-methoxybenzoic acid because the nitro group is an electron-withdrawing group that stabilizes the negative charge on the conjugate base through resonance, making it easier to lose a proton. The methoxy group, on the other hand, is an electron-donating group that destabilizes the conjugate base, making it less acidic.
Electrophilic Aromatic Substitution is an example of Ortho and para directing group and meta directing group.
salicytic acid is a ortho para directing group ....however check up on that ...i am not completely certain .. Actually, it is a meta-directing group, because of the carboxylic acid functional that the salicylic acid contains. Hope that was helpful.
This group attached to benzene ring acts as the ortho-para directing group due to Hyperconjugation.
orientation of incoming Nitro group is destined by already present group on benzene ring . if already present group is electron donating group, it will promote electron density at ortho and para position and , therefore, nitro group is formed on ortho and para position.
the ortho effect operates due to position of substituted group in ortho position. it increases the steric repulsion in 'amino' grup of aniline there by decreasing its basicity ,i.e tendency to accept proton.
The hydroxyl group (-OH) is an ortho para director in electrophilic aromatic substitution reactions because it is an activating group that stabilizes the developing positive charge on the ortho and para positions through resonance. This makes these positions more electron rich and therefore more susceptible to electrophilic attack.
Ortho-nitrobenzoic acid is more acidic than ortho-methoxybenzoic acid because the nitro group is an electron-withdrawing group that stabilizes the negative charge on the conjugate base through resonance, making it easier to lose a proton. The methoxy group, on the other hand, is an electron-donating group that destabilizes the conjugate base, making it less acidic.
ortho-para in benzene is meaningless these positions are for monosubstituted benzene. Meta is positions 3 and 5. Ortho is position 2 and 6 with relation to already attached group, para is 4 (opposite) to attached group.
Nitroso group (-NO) is deactivating because it withdraws electron density from the benzene ring due to its electronegativity. However, it is ortho para directing because it can donate electrons into the benzene ring through resonance, enhancing the electron density at the ortho and para positions.
Para-hydroxyacetophenone is more polar than ortho-hydroxyacetophenone due to the position of the hydroxyl group relative to the carbonyl group. In para-hydroxyacetophenone, the hydroxyl group is positioned across from the carbonyl group, leading to stronger hydrogen bonding interactions and increased polarity. This results in differences in physical properties such as solubility and boiling point between the two isomers.
I think you're asking about ortho-para directors. o,p directors are groups bonded to a benzene ring that direct additional groups in electrophilic aromatic substitution reactions to attach to the ortho and para positions of the benzene ring. Ortho is the position next to the group and para is the position across from the group on the benzene ring. o,p directors are electron donating groups such as methoxy groups. These groups stabilize the positive charge created in the intermediate when the electrophile adds to the ortho and para positions. o,p directors do not, however, stabilize the positive charge when the electrophile adds to the meta position and therefore only allow addition to the ortho and para positions (thus the name ortho-para director).
Ortho Tricyclen is made by Ortho.