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Negative temperatures mearly mean that they are below zero degrees. 0 degrees centigrade is the temperature that water freezes/melts at. Any chemical which is a gas at 0 dgrees Centigrade must have boiled at a lower temperautre than 0 degrees. If this temperature was for example 50 degrees lower than 0 degrees Centigrade you would write it as -50C, if it was 118 degrees below zero you would write it as -118C. However if the same temperatures were measured on the Kelvin temperature scale they would all be positive as it not possible to go lower than 0 degrees Kelvin. That temperature is called Absolute Zero.

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