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Disodium oxalate, often called simply sodium oxalate, is a sodium salt of oxalic acid with the molecular formula Na2C2O4. It is usually a white, crystalline, odorless powder, that decomposes at 250-270 °C.

Disodium oxalate can act as a reducing agent, and it may be used as a primary standard for standardizing potassium permanganate (KMnO4) solutions.

The mineral form of sodium oxalate is natroxalate. It is only very rarely found and restricted to extremely sodic conditions of ultra-alkaline pegmatites.[1]

Contents[hide]
  • 1 Preparation
  • 2 Reactions
  • 3 Biological activity
  • 4 References
PreparationSodium oxalate can be prepared through the neutralization of oxalic acid with NaOH in a 1:2 acid-to-base molar ratio. Half-neutralization can be accomplished with NaOH in a 1:1 ratio which produces NaHC2O4, monobasic sodium oxalate or sodium hydrogenoxalate. ReactionsSodium oxalate is used to standardize potassium permanganate solutions. It is desirable that the temperature of the titration mixture is greater than 60 °C to ensure that all the permanganate added reacts quickly. The kinetics of the reaction is complex, and the manganate(II) ions formed catalyze the further reaction between permanganate and oxalic acid (formed in situ by the addition of excess sulfuric acid). The final equation is as follows:[2]5H2C2O4 + 2KMnO4 + 3H2SO4 → K2SO4 + 2MnSO4 + 10CO2 + 8H2O Biological activityLike several other oxalates, sodium oxalate is toxic to humans. It can cause burning pain in the mouth, throat and stomach, bloody vomiting, headache, muscle cramps, cramps and convulsions, drop in blood pressure, heart failure, shock, coma, and possible death. Mean lethal dose by ingestion of oxalates is 10-15 grams (per MSDS).

Sodium oxalate, like citrates, can also be used to remove calcium ions (Ca2+) from blood plasma. It also prevents blood from clotting. Note that by removing calcium ions from the blood, sodium oxalate can impair brain function, and deposit calcium oxalate in the kidneys

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Why do you use sulphuric acid in titration of oxalate ion?

Sulfuric acid is used in titration of oxalate ion as it reacts with oxalate ion to form a white precipitate of calcium oxalate, which makes it easier to detect the end point of the titration. The strong acidity of sulfuric acid also helps in preventing the hydrolysis of the calcium oxalate precipitate.


Why ammonium oxalate is added in calcium carbonte solution?

ammonium oxalate is added to calcium carbonate because in the reaction between the two a crystal is formed that contain the Ca+2 ion. This is useful because if you have a sample of sodium carbonate with an unknown molarity you can use the oxalate to extract this calcium and determine what the molarity of the unknown solution was


How do you use the ion in a sentence?

You can use the word "ion" in a sentence to describe an electrically charged atom or molecule, such as "When sodium loses an electron, it becomes a positively charged ion."


The average adult human male has a total blood volume of 4.6 L If the concentration of sodium ion in this average individual is 0.139 M what is the mass of sodium ion circulating in the blood?

To find the mass of sodium ion circulating in the blood, you first need to calculate how many moles of sodium ions are present. With a concentration of 0.139 M and a blood volume of 4.6 L, you can use the formula moles = concentration x volume to find the moles of sodium ions. Then, multiply the moles by the molar mass of sodium (22.99 g/mol) to find the mass of sodium ion circulating in the blood.


Why do chemists write the formula for sodium chloride as NaCl?

Chemists use the chemical symbol for each element to write formulas. In the case of sodium chloride, sodium's symbol is Na and chlorine's symbol is Cl. By combining these symbols, NaCl represents the chemical formula for sodium chloride.

Related Questions

Why do you use sulphuric acid in titration of oxalate ion?

Sulfuric acid is used in titration of oxalate ion as it reacts with oxalate ion to form a white precipitate of calcium oxalate, which makes it easier to detect the end point of the titration. The strong acidity of sulfuric acid also helps in preventing the hydrolysis of the calcium oxalate precipitate.


Why ammonium oxalate is added in calcium carbonte solution?

ammonium oxalate is added to calcium carbonate because in the reaction between the two a crystal is formed that contain the Ca+2 ion. This is useful because if you have a sample of sodium carbonate with an unknown molarity you can use the oxalate to extract this calcium and determine what the molarity of the unknown solution was


How do you use the ion in a sentence?

You can use the word "ion" in a sentence to describe an electrically charged atom or molecule, such as "When sodium loses an electron, it becomes a positively charged ion."


Assume you had a mixture of solid na2co3 and nacl could you use only h2so4 to determine whether or not na2co3 was present explain?

Yes, you could use H2SO4 to determine the presence of Na2CO3 in the mixture. When H2SO4 is added to the mixture, effervescence will be observed due to the reaction between Na2CO3 and H2SO4, producing CO2 gas. This effervescence confirms the presence of Na2CO3 in the mixture.


The average adult human male has a total blood volume of 4.6 L If the concentration of sodium ion in this average individual is 0.139 M what is the mass of sodium ion circulating in the blood?

To find the mass of sodium ion circulating in the blood, you first need to calculate how many moles of sodium ions are present. With a concentration of 0.139 M and a blood volume of 4.6 L, you can use the formula moles = concentration x volume to find the moles of sodium ions. Then, multiply the moles by the molar mass of sodium (22.99 g/mol) to find the mass of sodium ion circulating in the blood.


Why do chemists write the formula for sodium chloride as NaCl?

Chemists use the chemical symbol for each element to write formulas. In the case of sodium chloride, sodium's symbol is Na and chlorine's symbol is Cl. By combining these symbols, NaCl represents the chemical formula for sodium chloride.


Which is the correct order to use in writing the name of an ionic compoun?

The correct order is to write the metal ion first followed by the non-metal ion. For example, sodium chloride or calcium carbonate.


Calcium chloride and sodium hydroxide is equals?

It would be unethical to use this service to answer exam or graded questions. CaCl2 + 2NaOH --> 2NaCl + Ca(OH)2 Calcium Chloride + Sodium Hydroxide --> Sodium Chloride + Calcium Hydroxide Why: Ca ion has 2+ charge Cl ion has 1- charge Na ion has 1+ charge OH polyatomic ion has 1- charge


How many electrons are lost by 42 g of sodium when its atom are oxidized to ions?

The ion sodium is Na + so we have a one to one loss and can just find the atoms of sodium in the mass. 42 grams sodium (1 mole Na/22.99 grams)(6.022 X 1023/1 mole Na) = 1.1 X 1024 atoms of sodium -----------------------------------------now, Every atom of sodium donates one electron to become a sodium ion. So. We have.....1.1 X 1024 .......electrons lost by 42 grams of sodium ionized.


Use a diagram to show ions are formed when a sodium atom comes into close contact with a chlorine atom?

I'm unable to create diagrams. When a sodium atom comes into close contact with a chlorine atom, the sodium atom donates one electron to the chlorine atom. This results in the sodium atom forming a positively charged sodium ion (Na+) and the chlorine atom forming a negatively charged chloride ion (Cl-), as they achieve stable electron configurations.


How do you test for sodium ions and potassium ions when both are present?

One way to test for sodium ions and potassium ions when both are present is to use flame tests. Each ion produces a unique colored flame when burned. Another method is to use ion-selective electrodes that can differentiate between sodium and potassium ions based on their specific affinity for the electrodes. Separation techniques such as ion exchange chromatography can also be used to separate and quantify sodium and potassium ions.


What is the chemical formula for dihydrogen sulfate?

It is: H2SO4 ============================== While there is certainly the chemical with the formula H2SO4, there is no "dihydrogen sulfate" name. H2SO4 is called sulfuric acid, and that is the only name recognized by the IUPAC for H2SO4. So if you are naming H2SO4 then use "sulfuric acid", do not use "dihydrogen sulfate."