Superman. He can fly. He would fly him all the way to fortress of solitude and fight him there. Hawkeye could only have kryptonite arrows to defeat Superman. Superman would burn him on the arm and punch him in the face and throw him and then punch him into space and then fly him to Metropolis and punch him 7 times to knock him out. Superman wins all the way.
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Superman would break his weapons. Superman has no options. He'd punch Deadpool into space. Deadpool has only 2 options. He'd either fight Superman and lose or he'd go away. Superman has a choice. Deadpool would still stick up to Superman. Superman would fly him to the air and drop him and Deadpool's power will be gone. Easy win. Superman all the way.