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Leafy vegetables are primarily composed of water. During cooking, water is released from the vegetables either in the form of steam or liquid in the cooking pan (that's what makes the "sizzle" sound when you cook). When water is removed from the plants, there is simply not much left, so they appear to "shrink".

To help the release of water, you can add salt, which helps to draw out the moisture.

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13y ago

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